Skip to main navigation menu Skip to main content Skip to site footer

Science

Vol 9 No 1 (2024): June

Applications of Chitosan Polymer Membrane to Removal Methyl Orange Dye from Aqueous Solutions
Aplikasi Membran Polimer Kitosan untuk Menghilangkan Pewarna Metil Oranye dari Larutan Berair



(*) Corresponding Author
DOI
https://doi.org/10.21070/acopen.9.2024.8934
Published
May 13, 2024

Abstract

In this study, membranes made from chitosan, a natural polymer derived from shrimp shells, were investigated for their ability to remove toxic methyl orange (MO) dye from water. The membranes were characterized using infrared spectroscopy, and the maximum absorption wavelength of MO dye was determined via UV-Visible spectrophotometry. Solutions of varying MO concentrations were passed through the chitosan membranes, and their absorbance was measured before and after filtration. Results showed high removal rates ranging from 85% to 95%, with the highest efficiency observed at 20 ppm MO concentration. This research highlights the potential of chitosan membranes as effective and sustainable solutions for water purification, addressing a crucial environmental and health concern posed by toxic dye pollution.

Highlights:

  1. High removal rates: Chitosan membranes remove dye efficiently (85%-95%).
  2. Eco-friendly: Derived from shrimp shells, chitosan offers sustainable water purification.
  3. Advanced analysis: Infrared spectroscopy and UV-Visible spectrophotometry characterize membrane properties.

Keywords: Chitosan membranes, Water pollution, Methyl orange dye, Removal efficiency, Environmental sustainability

References

  1. Here's the list of references in IEEE style:
  2. Y. Roiter, S. Minko, "AFM Single Molecule Experiments at the Solid-Liquid Interface: In Situ Conformation of Adsorbed Flexible Polyelectrolyte Chains", *J. Amer. Chem. Soc.*, vol. 127, 1997.
  3. C. Paul, C. Painter, M. Michael, "Fundamentals of Polymer Science: An Introductory Text", Techonomic Pub. Co., Lancaster, 1997.
  4. N.G. McCrum, C.P. Buckley, C.B. Bucknall, “Principles of Polymer Engineering”, Oxford University Press, Canada, 1997.
  5. C. Chassenieux, et al., "Biopolymers: State of the Art, New Challenges, and Opportunities", *Handbook of Biopolymer-Based Materials: From Blends and Composites to Gels and Complex Networks*, pp. 1-6, 2013.
  6. J. Li, J.F. Revol, R.H. Marchessault, "Effect of Degree of Chitin Crystallites", *J. Appl. Polym. Sci.*, vol. 65, no. 2, p. 373, 1997.
  7. M.N.V. Ravi Kumar, "A Review of Chitin and Chitosan Applications", *Reactive & Functional Polymers*, vol. 46, p. 1, 2000.
  8. P.M. Visakh and S. Thomas, "Preparation of Bionanomaterials and Their Polymer Nanocomposites from Waste and Biomass", *Waste Biomass Valor*, vol. 1, p. 121, 2010.
  9. R.A.A. Muzzarelli, C. Jeuniaux, G.W. Gooday, "Chitin in Nature and Technology", Plenum Press, New York, 1986.
  10. J.I. Kadokawa, A. Takegawa, S. Mine, and K. Prasad, “Preparation of Chitin Nano Whiskers Using an Ionic Liquid and Their Composite Materials with Poly(Vinyl Alcohol)”, *Carbohydr. Polym.*, vol. 84, no. 4, p. 1408, 2011.
  11. H. Sashiwa, N. Kawasaki, A. Nakayama, E. Muraki, N. Yamamoto, H. Zhu, N. Nagano, Y. Omura, H. Saimoto, Y. Shigemasa, S. Aiba, "Chemical Modification of Chitosan. 13.(1) Synthesis of Organosoluble, Palladium Adsorbable, and Biodegradable Chitosan Derivatives toward the Chemical Plating on Plastics", *Biomacromol*, vol. 3, p. 1120, 2002.
  12. N.L. Yusof, A. Wee, L.Y. Lim, E. Khor, "Flexible Chitin Films as Potential Wound-Dressing Materials: Wound Model Studies", *J. Biomed. Mater. Res. Part A*, vol. 66A, p. 224, 2003.
  13. R.A. Morganti, G. Muzzarelli, P. Palombo, G. Biagini, M. Belmonte, F. Giantomassi, F. Orlandi, C. Muzzarelli, "Chitin Nanofibrils/Chitosan Glycolate Composites as Wound Medicaments", *Carbohydr. Polym*, vol. 70, p. 274, 2007.
  14. E.S. De Alvarenga, "Characterization and Properties of Chitosan", in *Biotechnology of Biopolymers*, M. Elnashar (Editor), InTech, Rijeka, Croatia, 2011.
  15. I. Younes and M. Rinaudo, "Chitin and Chitosan Preparation from Marine Sources: Structure, Properties, and Applications", *Mar. Drugs*, vol. 13, no. 3, p. 1133, 2015.
  16. N. Jonge, Y. Lamy, K. Schoots, and T.H. Oosterkamp, "High Brightness Electron Beam from a Multi-Walled Carbon Nanotube", *Nature*, vol. 420, p. 393, 2002.
  17. M.S. Dresselhaus and I.L. Thomas, "Alternative Energy Technologies", *Nature*, vol. 414, p. 332, 2001.
  18. S. Pandharipande and P.H. Bhagat, "Synthesis of Chitin From Crab Shells and Its Utilization in Preparation of Nanostructured Film", *Synthesis*, vol. 5, no. 5, 2016.
  19. N. Al-Bastaki, “Removal of Methyl Orange Dye and Na2so4 Salt from Synthetic Waste Water Using Reverse Osmosis”, *Chem. Eng. Process. Process Intensif.*, vol. 43, no. 12, pp. 1561–1567, 2004.
  20. A. Arafat, S.A. Samad, S.M. Masum, and M. Moniruzzaman, "Preparation and Characterization of Chitosan from Shrimp Shell Waste", *Int. J. Sci. & Eng. Res.*, vol. 6, no. 5, p. 538-541, 2015.
  21. S.H. Mutasher, A.A. Salih, H.S. Al-Lami, "Preparation of Some Chitosan Derivatives and Study Their Effect on Human Genetic Material", *Der Pharma Chemica*, vol. 8, no. 11, p. 125-134, 2016.
  22. M.H. Zaboon, A.A. Saleh, H.S. Al-Lami, "Comparative Cytotoxicity and Genotoxicity Assessments of Chitosan Amino Acid Derivative Nanoparticles Toward Human Breast Cancer Cell Lines", *Egyptian J. Chem.*, vol. 62, no. 11, p. 1-2, 2019.
  23. A. Croitoru et al., "Materials Chitosan / Graphene Oxide Nanocomposite Water Purification", pp. 1–13.
  24. S. Pandharipande and P.H. Bhagat, "Synthesis of Chitin From Crab Shells and Its Utilization in Preparation of Nanostructured Film", *Synthesis*, vol. 5, no. 5, 2016.
  25. I. Younes and M. Rinaudo, "Chitin And Chitosan Preparation From Marine Sources: Structure, Properties and Applications", *Marine Drugs*, vol. 13, no. 3, p. 1133-1174, 2015.
  26. S. Wafiroh, M. Wathoniyyah, A. Abdulloh, Y.
  27. Rahardjo, M.Z. Fahmi, "Application of Glutaraldehyde-Crosslinked Chitosan Membranes from Shrimp Shell Waste on Production of Biodiesel from Calophyllum Inophyllum Oil", *Chem. & Chem. Tech.*, vol. 11, no. 1, p. 65–70, 2017.
  28. G. Muñoz, C. Valencia, N. Valderruten, E. Ruiz-Durántez, and F. Zuluaga, "Extraction of Chitosan from Aspergillus Niger Mycelium and Synthesis of Hydrogels for Controlled Release of Betahistine", *Reactive and Functional Polymers*, vol. 91, p. 1-10, 2015.
  29. Y. Liu, Y. Huang, A. Xiao, H. Qiu, and L. Liu, "Preparation of Magnetic Fe3O4/MIL-88A Nanocomposite and Its Adsorption Properties for Bromophenol Blue Dye in Aqueous Solution", *Nanomaterials*, vol. 9, no. 1, 2019.

Downloads

Download data is not yet available.