Vol 10 No 1 (2025): June (In Progress)
Science

Sustainable Approaches to Synthesis SnO2/MWCNT Nanocomposite Using Eggplant Extract: Study Structural Optical and Morphological Properties
Pendekatan Berkelanjutan untuk Sintesis Nanokomposit SnO2/MWCNT Menggunakan Ekstrak Terong: Mempelajari Sifat Optik dan Morfologi Struktural


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(*) Corresponding Author
Published January 10, 2025
Keywords
  • SnO­­­2  NPs,
  • SnO2/MWCNT,
  • Eggplant Extract,
  • green synthesis
How to Cite
Kadhim , O. J., & Thamer , A. A. (2025). Sustainable Approaches to Synthesis SnO2/MWCNT Nanocomposite Using Eggplant Extract: Study Structural Optical and Morphological Properties. Academia Open, 10(1), 10.21070/acopen.10.2025.10472. https://doi.org/10.21070/acopen.10.2025.10472

Abstract

To develop eco-friendly methods in nanotechnology, an innovative approach to the fabrication of SnO₂/MWCNT nanocomposites using an easily used yet effective green method was achieved. This study shows a sustainable route to highly reducing chemical synthesis, using the natural reducing properties of the eggplant extract. Working successfully, the research was able to create a hybrid nanomaterial comprised of tin oxide (SnO₂) and multi walled carbon nanotubes (MWCNTs) using a simple co-precipitation technique. Combining SnO₂ and MWCNT resulted in a nanocomposite with an intriguing transformation from nanotubular to flower-like structures and uniform distribution of the particles. Detailed analysis showed a crystallite size of ~ 21.75 nm for pure SnO₂ up to 38.98 nm in the hybrid form and retained good uniformity ~ 45.84 nm. Most importantly, the integration of MWCNTs yielded an optimized bandgap reduction from 3.5 to 3.1 eV, improving the material’s light absorption ability. Such improvement opens up exciting applications in photocatalysis, gas sensing and energy storage devices. This eco friendly synthesis method is proven to be viable for creating green advanced nanomaterials, which not only provides proof of concept for green approach in creating advanced nanomaterials but allows for more sustainable practices in nanotechnology development while keeping the high performance standards needed for practical applications.

Highlights:

  1. Eco-friendly SnO₂/MWCNT synthesis using eggplant extract
  2. Green nanotechnology: improved bandgap, structure, and uniformity
  3. Applications in photocatalysis, gas sensing, and energy storage

Keywords: SnO­­­NPs, SnO2/MWCNT, Eggplant Extract, green synthesis

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References

  1. M. A. Darwish, W. Abd-Elaziem, A. Elsheikh, and A. A. Zayed, "Advancements in nanomaterials for nanosensors: a comprehensive review," Nanoscale Advances, vol. 6, no. 16, pp. 4015-4046, 2024/08/06/ 2024, doi: https://doi.org/10.1039/d4na00214h.
  2. Y. E. Tasisa, T. K. Sarma, T. K. Sahu, and R. Krishnaraj, "Phytosynthesis and characterization of tin-oxide nanoparticles (SnO2-NPs) from Croton macrostachyus leaf extract and its application under visible light photocatalytic activities," Scientific Reports, vol. 14, no. 1, p. 10780, 2024.
  3. A. I. Osman et al., "Synthesis of green nanoparticles for energy, biomedical, environmental, agricultural, and food applications: A review," Environmental Chemistry Letters, vol. 22, no. 2, pp. 841-887, 2024/04/01 2024, doi: 10.1007/s10311-023-01682-3.
  4. Y. T. Gebreslassie and H. G. Gebretnsae, "Green and cost-effective synthesis of tin oxide nanoparticles: a review on the synthesis methodologies, mechanism of formation, and their potential applications," Nanoscale research letters, vol. 16, no. 1, p. 97, 2021.
  5. K. Aguir, S. Bernardini, B. Lawson, and T. Fiorido, "8 - Trends in metal oxide thin films: Synthesis and applications of tin oxide," in Tin Oxide Materials, M. O. Orlandi Ed.: Elsevier, 2020, pp. 219-246.
  6. W. Matysiak, T. Tański, W. Smok, and O. Polishchuk, "Synthesis of hybrid amorphous/crystalline SnO2 1D nanostructures: investigation of morphology, structure and optical properties," Scientific reports, vol. 10, no. 1, p. 14802, 2020.
  7. F. Khan, M. Shariq, M. Asif, M. A. Siddiqui, P. Malan, and F. Ahmad, "Green Nanotechnology: Plant-Mediated Nanoparticle Synthesis and Application," Nanomaterials, vol. 12, no. 4, p. 673, 2022. [Online]. Available: https://www.mdpi.com/2079-4991/12/4/673.
  8. N. M. Hung et al., "Carbon nanotube-metal oxide nanocomposite gas sensing mechanism assessed via NO2 adsorption on n-WO3/p-MWCNT nanocomposites," Ceramics International, vol. 46, no. 18, Part A, pp. 29233-29243, 2020/12/15/ 2020, doi: https://doi.org/10.1016/j.ceramint.2020.08.097.
  9. T. A. Dontsova, S. V. Nagirnyak, V. V. Zhorov, and Y. V. Yasiievych, "SnO 2 nanostructures: Effect of processing parameters on their structural and functional properties," Nanoscale research letters, vol. 12, pp. 1-7, 2017.
  10. G. Devi, H. Hamoon, A. Nanaji, K. Reddy, B. Sreedhar, and J. Ramana Rao, "A Simple Sol Gel Protocol Towards Synthesis Of Semiconducting Oxide Nanomaterial," 2011.
  11. M. Morsy, I. Gomaa, W. Taha, A. E. M. A. Elhamid, H. Shoukry, and M. Mokhtar, "Optimization and surface functionalization of carbon nanotubes using different hierarchical metal oxide nanoparticles," HBRC Journal, vol. 19, no. 1, pp. 509-521, 2023.